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Comparison of Transparent Polymer Types and Properties | Weather Resistance and Moisture Absorption

Transparent resins are used in a wide range of fields, including optical components, housings, covers, medical devices, and outdoor applications.

This article summarizes the properties of typical transparent resins and introduces the features and advantages of Tefabloc™ CP, which boasts excellent weather resistance and moisture absorption.

Transparent polymers

Transparent resins vary greatly in transparency, weather resistance, moisture absorption, and processability depending on the material. Selecting the appropriate material for the application is crucial. Below are some major transparent resins, their characteristics, and examples of applications.

PS (Polystyrene)

PS is a general-purpose resin characterized by its high transparency and low cost.

• High transparency and high gloss

• Good moldability

- Impact resistance and weather resistance are relatively low.

Examples of uses: Indoor covers, simple containers, display components

PMMA (acrylic resin)

PMMA is a transparent resin with excellent optical properties and weather resistance.

• Very high transparency

• Weather resistance proven even in outdoor applications

- It has moderately high moisture absorption.

Examples of applications: lighting covers, signs, optical components

PC (Polycarbonate)

PC is an engineering plastic that combines transparency and impact resistance.

• High impact resistance and heat resistance

• High mechanical strength

• Protection against yellowing caused by ultraviolet light is necessary.

• Examples of applications: Outdoor covers, protective components, electronic equipment enclosures

DURABIO™

DURABIO™ is a bioengineered plastic unique to Mitsubishi Chemical, designed to combine the high impact resistance and heat resistance of PC with the high transparency and surface hardness of PMMA, while using plant-derived isosorbide as its main raw material.

• High transparency and low birefringence (optical properties equivalent to PMMA)

• Excellent UV resistance and weather resistance (less yellowing, which is a problem with PCs)

•High surface hardness and scratch resistance

• Plant-derived and BPA-free

• Examples of applications: Automotive interior and exterior design parts, in-vehicle transparent panels, optical films, high-end cosmetic containers

COP (Cycloolefin Polymer)

COP is a cyclic olefin polymer, a transparent resin used in films and medical applications.

・Low moisture absorption

• High transparency and film processability

• High cost of raw materials

Examples of applications: Optical films, medical packaging materials

COC (Cycloolefin Copolymer)

Like COP, COC is a cyclic olefin polymer and is a transparent resin with excellent optical properties.

・Low moisture absorption

• Low birefringence, high transparency, high rigidity

Film processing is difficult.

• Examples of applications: Lenses and optical components

Tefabloc™ CP

Tefabloc™ CP is a transparent resin with excellent weather resistance and adhesion to dissimilar materials.

• High transparency

• Excellent weather resistance and low moisture absorption

- Heat welding with other resins is possible.

• High cost of raw materials

• Example applications: High-weather-resistant outdoor covers, integrated functional components

Weather resistance

For outdoor applications and products intended for long-term use, weather resistance to ultraviolet rays, heat, and humidity significantly impacts the product's lifespan.

Weather resistance of each resin

Resins and materials

Relative evaluation of weather resistance

Supplementary information regarding the evaluation

PS

△ Limited

It may not be suitable for long-term outdoor use.

PMMA (ACRYPET™)

◎ Very high

Proven track record of outdoor use

PC (XANTAR™)

○ High

Measures to prevent yellowing due to ultraviolet light may be necessary.

Biopolycarbonate (DURABIO™)

◎ Very high

It exhibits weather resistance similar to PMMA.

COP

△ Limited

Prior evaluation is necessary depending on the usage environment.

COC

○ High

Prior evaluation is necessary depending on the usage environment.

Amorphous olefin compound (Tefabloc™ CP)

◎ Very high

Material design that achieves both transparency and weather resistance is possible.

Physical properties can be adjusted according to customer requirements.

Color change due to accelerated weathering test (60°C, with rain)

Hygroscopic

Moisture absorption of each resin

Moisture absorption is an important factor that affects dimensional stability, appearance quality, and optical properties.

Low-hygroscopic materials are suitable for outdoor applications, precision components, and optical applications.

PS

Very low

PMMA

expensive

PC (XANTAR™)

Slightly expensive

DURABIO™

Medium

COP

Very low

COC

Very low

Tefabloc™CP

Very low

Weather-resistant polymers; Tefabloc™ CP

Tefabloc™ CP is a material that achieves a high level of weather resistance, low moisture absorption, and design flexibility in transparent resin applications.

Excellent weather resistance and low moisture absorption

• Maintains transparency even after long-term outdoor exposure

- Minimal dimensional change due to moisture absorption

- Minimizes external deterioration and achieves high reliability.

Suitable for outdoor covers and light-transmitting components.

Heat-weldability with other resins

Tefabloc™ CP can be heat-welded with olefin resins.

- Can be integrally molded with general-purpose resins such as PP and PE.

By leveraging these characteristics, it is possible to rationalize costs and mechanical properties by applying expensive transparent resin only to the necessary parts, rather than using it for the entire enclosure.

Tefabloc™ CP also includes grades that can transmit UV-C light, which is not transmitted by typical transparent resins. We will propose the optimal material to suit your usage environment and required performance.

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The above information is based on the latest available information as of the date of creation and may be revised in the future based on new information.

Furthermore, this information is provided as general technical information and reference material, and we do not guarantee the accuracy or completeness of the content.

Product performance and characteristics may vary depending on usage conditions, processing conditions, etc. The final decision regarding applicability and design is the customer's responsibility.

We will check the regulations of each country regarding the export of chemical products and then respond whether or not we can provide them. Please be sure to include information such as the exporting country.

Depending on the product, we may suggest a different grade or may not be able to provide the product at all.

Mitsubishi Chemical Corporation

Mitsubishi Chemical Corporation
Polymer Compounds Business Group

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